Will go through this at home and post some more info. I want to take a look at their Synology Account services before I post here. My method is the regular port forwarding thing that you're trying to use and I suspect the new account services makes it easier.
(And yes, you do need some more config in your port forwarding setup - which you have outlined in red)
https://account.synology.com/support...r.php?lang=enu